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fourth-ray Fourth Ray Keep Clear Clarifying Toner

fourth-ray Fourth Ray Keep Clear Clarifying Toner lists 27 ingredients on its label, 26 decoded. See what each one does, its irritancy and comedogenic tendency, and its status in national inventories.

Ingredients overview

Label order. Colour is our internal rating: green routine, yellow restricted or worth a look, red prohibited or high-risk, grey not yet decoded.

Ingredients are listed in label order; the order reflects the label only, not exact concentrations.

  1. Water
  2. Hamamelis Virginiana Water
  3. Butylene Glycol
  4. Glycerin
  5. Alcohol
  6. Polysorbate 20
  7. Panax Ginseng Root Extract
  8. Salix Nigra Bark Extract
  9. Lactobacillus/Papaya Fruit Ferment Extract
  10. Quartz
  11. Citrus Limon Fruit Extract
  12. Citrus Aurantium Dulcis Fruit Extract
  13. Melaleuca Alternifolia Leaf Oil
  14. Eucalyptus Globulus Leaf Oil
  15. Camellia Sinensis Leaf Extract
  16. Saccharum Officinarum Extract
  17. Acer Saccharum Extract
  18. Helianthus Annuus Seed Oil
  19. Vaccinium Myrtillus Fruit Extract
  20. Jania Rubens Extract
  21. Allantoin
  22. Sodium Carrageenan
  23. Gluconolactone
  24. Citric Acid
  25. Tartaric Acid
  26. Sodium Benzoate
  27. Phenoxyethanol

Highlights

Free of parabensFree of siliconesFree of sulfatesFree of mineral oilFree of formaldehyde releasersContains alcoholContains PEGContains EU-26 allergensContains fragranceContains essential oils

Key ingredients

ANTIPLAQUE
Water
ASTRINGENT
Hamamelis Virginiana Water
HUMECTANT
Butylene Glycol
DENATURANT
Glycerin
ANTIFOAMING
Alcohol
SURFACTANT - EMULSIFYING
Polysorbate 20
SKIN CONDITIONING - EMOLLIENT
Panax Ginseng Root Extract
SKIN PROTECTING
Salix Nigra Bark Extract

Other ingredients

Lactobacillus/Papaya Fruit Ferment ExtractQuartzCitrus Limon Fruit ExtractCitrus Aurantium Dulcis Fruit ExtractMelaleuca Alternifolia Leaf OilEucalyptus Globulus Leaf OilCamellia Sinensis Leaf ExtractSaccharum Officinarum ExtractAcer Saccharum ExtractHelianthus Annuus Seed OilVaccinium Myrtillus Fruit ExtractJania Rubens ExtractAllantoinSodium CarrageenanGluconolactoneCitric AcidTartaric AcidSodium BenzoatePhenoxyethanol

Skim through

IngredientWhat it doesIrr. · Com.Rating
WaterANTIPLAQUE, SKIN CONDITIONING, SOLVENT0 · 0Green
Hamamelis Virginiana WaterASTRINGENT, HAIR CONDITIONING, SKIN CONDITIONING, SOOTHINGGreen
Butylene GlycolHUMECTANT, FRAGRANCE, SKIN CONDITIONING, SOLVENT, VISCOSITY CONTROLLING0 · 0Green
GlycerinDENATURANT, HAIR CONDITIONING, HUMECTANT, ORAL CARE, SKIN PROTECTING, SOLVENT, VISCOSITY CONTROLLING, PERFUMING, FRAGRANCE, SKIN CONDITIONING - HUMECTANT0 · 0Green
AlcoholANTIFOAMING, ANTIMICROBIAL, ASTRINGENT, FRAGRANCE, SOLVENT, VISCOSITY CONTROLLING1 · 0Yellow
Polysorbate 20SURFACTANT - EMULSIFYING, SURFACTANT - CLEANSING0 · 0Green
Panax Ginseng Root ExtractSKIN CONDITIONING - EMOLLIENT, HAIR CONDITIONING, SKIN PROTECTING, TONICGreen
Salix Nigra Bark ExtractSKIN PROTECTING1 · 0Green
Lactobacillus/Papaya Fruit Ferment ExtractNot decoded yet
QuartzABRASIVE2 · –Green
Citrus Limon Fruit ExtractFRAGRANCE, SKIN CONDITIONING - MISCELLANEOUS, SKIN CONDITIONING - OCCLUSIVE · 限制 II/3581 · 0Green
Citrus Aurantium Dulcis Fruit ExtractFRAGRANCE, SKIN CONDITIONING1 · 0Green
Melaleuca Alternifolia Leaf OilANTIOXIDANT, FRAGRANCE, SKIN PROTECTING, PERFUMING, SKIN CONDITIONING - MISCELLANEOUS2 · 0Green
Eucalyptus Globulus Leaf OilSKIN CONDITIONING, PERFUMING · 限制 III/3553 · –Green
Camellia Sinensis Leaf ExtractANTIMICROBIAL, ANTIOXIDANT, ASTRINGENT, SKIN CONDITIONING - EMOLLIENT, HUMECTANT, FRAGRANCE, ORAL CARE, SKIN CONDITIONING, SKIN PROTECTING, TONIC, UV ABSORBER1 · 0Green
Saccharum Officinarum ExtractMOISTURISING, SKIN CONDITIONING0 · –Green
Acer Saccharum ExtractSKIN CONDITIONINGGreen
Helianthus Annuus Seed OilSKIN CONDITIONING - EMOLLIENT, SOLVENT, SKIN CONDITIONING - MISCELLANEOUS, SKIN CONDITIONING - OCCLUSIVE0 · 0Green
Vaccinium Myrtillus Fruit ExtractSKIN CONDITIONING - MISCELLANEOUS0 · –Green
Jania Rubens ExtractSKIN CONDITIONING0 · –Green
AllantoinSKIN CONDITIONING, SKIN PROTECTING, SOOTHING0 · 0Green
Sodium CarrageenanANTISTATIC, BINDING, EMULSION STABILISING, FILM FORMING, VISCOSITY CONTROLLING0 · 0Green
GluconolactoneCHELATING, SKIN CONDITIONING2 · 1Green
Citric AcidBUFFERING, CHELATING, FRAGRANCE1 · 0Green
Tartaric AcidBUFFERING, FRAGRANCE3 · 0Green
Sodium BenzoateANTICORROSIVE, FRAGRANCE, PRESERVATIVE · 限制 V/10 · –Yellow
PhenoxyethanolANTIMICROBIAL, PRESERVATIVE · 限制 V/291 · 0Yellow

Ingredients explained

Water
Primary solvent and base; requires preservative system to prevent microbial growth
Hamamelis Virginiana Water
Hamamelis water; tannins/flavonoids for astringent and soothing; low conc, generally well-tolerated
Butylene Glycol
Polyol humectant and solvent at 1–5%; aids solubilization, light feel
Glycerin
Workhorse humectant at 3–10%; tacky at high levels, pair with occlusives
Alcohol
Ethanol for solubility/drying at 5-15%; high conc. is drying/irritating, avoid lip/eye, low residue, balance with humectants.
Polysorbate 20
Non-ionic emulsifier and cleansing surfactant; contains PEG, control microbial load.
Panax Ginseng Root Extract
Botanical extract for skin and hair conditioning; activity and irritation risk vary by source/purity, patch test for sensitive skin
Salix Nigra Bark Extract
Black willow bark extract with natural salicylic acid precursors; for soothing and exfoliation, test on sensitive skin at low levels.
Lactobacillus/Papaya Fruit Ferment Extract
Not decoded yet
Quartz
Mineral abrasive for physical exfoliation; particle size and polish critical, high hardness may damage stratum corneum.
Citrus Limon Fruit Extract
Lemon fruit extract for fragrance and occlusive moisturizing; contains furanocoumarins, photosensitivity caution advised.
Citrus Aurantium Dulcis Fruit Extract
Citrus peel extract, provides fragrance and astringency; photosensitive due to furanocoumarins; caution in daytime or remove photoactives.
Melaleuca Alternifolia Leaf Oil
Tea tree oil, antibacterial and sebum regulating; highly sensitizing at concentrate level, dilute; avoid on broken skin.
Eucalyptus Globulus Leaf Oil
Eucalyptus leaf oil, strong essential oil; high irritation, strictly limited usage
Camellia Sinensis Leaf Extract
Green tea extract for antioxidant/astringent; contains caffeine, possible irritation in sensitive skin.
Saccharum Officinarum Extract
Sugarcane extract, mainly moisturizing and conditioning; use at low levels; prone to microbes, needs preservatives.
Acer Saccharum Extract
Maple extract; NMF/AA source; gentle humectant, no public irritant/comedogenic data
Helianthus Annuus Seed Oil
Sunflower seed oil for emollient/occlusive; high linoleic acid, low comedogenicity.
Vaccinium Myrtillus Fruit Extract
Bilberry extract; anthocyanin rich; gentle antioxid/conditioning, no pub comed data
Jania Rubens Extract
Jania rubens extract with polysaccharides; moisturizing skin conditioner, check algal batch stability.
Allantoin
Skin soother at 0.5-2%; promotes cell regeneration
Sodium Carrageenan
Seaweed-derived thickener and stabilizer, 0.5-1.5% adjusts viscosity; sensitive to ions, test compatibility with cationic surfactants.
Gluconolactone
Multifunctional agent for chelation and permeation; acidic, may irritate at high levels, buffer recommended.
Citric Acid
Buffer and chelator at 0.1–2%; adjusts pH, may irritate sensitive skin at low pH
Tartaric Acid
Small-molecule organic acid used as buffer and antioxidant; highly irritating at high levels, caution for sensitive skin
Sodium Benzoate
Preservative booster, effective below pH 4.5; combinable with sorbates
Phenoxyethanol
Broad-spectrum preservative at ≤1%; may irritate sensitive eye areas, often paired with ethylhexylglycerin

Source: full ingredient list published on the product label, collected 2026-09-19. Ratings are our internal reading, not a regulatory conclusion. · Product page

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